Piezoelectricity

Piezoelectricity is the electric charge that accumulates in certain solid materials (such as crystals, certain ceramics, and biological matter such as bone, DNA and various proteins) in response to applied mechanical stress. The word piezoelectricity means electricity resulting from pressure. It is derived from the Greek piezo or piezein, which means to squeeze or press, and electric or electron, which means amber, an ancient source of electric charge.

Materials-

Many materials, both natural and synthetic, exhibit piezoelectricity:

• Naturally occurring crystals
• Quartz
• Berlinite (AlPO4), a rare phosphate mineral that is structurally identical to quartz
• Sucrose (table sugar)
• Rochelle salt
• Topaz
• Tourmaline-group minerals
• Lead titanate (PbTiO3).

The action of piezoelectricity in Topaz can probably be attributed to ordering of the (F,OH) in its lattice, which is otherwise centrosymmetric: Orthorhombic Bipyramidal (mmm). Topaz has anomalous optical properties which are attributed to such ordering.

Bone

Dry bone exhibits some piezoelectric properties. Studies of Fukada et al. showed that these are not due to the apatite crystals, which are centrosymmetric, thus non-piezoelectric, but due to collagen. Collagen exhibits the polar uniaxial orientation of molecular dipoles in its structure and can be considered as bioelectret, a sort of dielectric material exhibiting quasipermanent space charge and dipolar charge. Potentials are thought to occur when a number of collagen molecules are stressed in the same way displacing significant numbers of the charge carriers from the inside to the surface of the specimen. Piezoelectricity of single individual collagen fibrils was measured using piezoresponse force microscopy, and it was shown that collagen fibrils behave predominantly as shear piezoelectric materials.

Other natural materials

Biological materials exhibiting piezoelectric properties include:

• Tendon
• Silk
• Wood due to piezoelectric texture
• Enamel
• Dentin
• DNA
• Viral proteins, including those from bacteriophage. One study has found that thin films of M13 bacteriophage can be used to construct a piezoelectric generator sufficient to operate a liquid crystal display.